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"A chromium terephthalate-based solid with
unusually large pore volumes and surface area," by G. Ferey and 6
others, Science, 309(5743): 2040-2, 23 September 2005.
[Authors' affiliations: Universite de
Versailles, France; Institut Universitaire de France, Paris; Royal
Institution, London, U.K.; European Radiation Synchrotron Facility, Grenoble,
France]
Abstract: "We combined targeted
chemistry and computational design to create a crystal structure for porous
chromium terephthalate, MIL-101, with very large pore sizes and surface
area. Its zeotype cubic structure has a giant cell volume (~702,000 cubic
angstroms), a hierarchy of extra-large pore sizes (~30 to 34 angstroms), and
a Langmuir surface area for N(2) of ~5900 plus/minus 300 square meters per
gram. Beside the usual properties of porous compounds, this solid has
potential as a nanomold for monodisperse nanomaterials, as illustrated here
by the incorporation of Keggin polyanions within the cages."
This 2005 report from Science was cited
19 times in current journal articles indexed by Thomson
Scientific during May-June 2007. During that two-month period, only one
other chemistry paper published in the last two years (aside from reviews)
attracted a higher number of citations. Prior to the most recent bimonthly
count, citations to the paper have accrued as follows:
March-April 2007: 16 citations
January-February 2007: 8
November-December 2006: 14
September-October 2006: 8
July-August 2006: 15
May-June 2006: 13
March-April 2006: 11
January-February 2006: 3
November-December 2005: 2
September-October 2005: 1
Total citations to date: 110
SOURCE: Hot
Papers Database (Included with a subscription to the print newsletter Science
Watch®, available from the
Research Services Group. Packaged on a CD that is mailed with each Science
Watch issue, the Hot
Papers Database contains data on hundreds of highly cited papers published
during the last two years. User interface permits searching by author,
organization, journal, field, and more. Total citations, as well as citations
accrued during successive bimonthly periods, can be assessed and graphed. An
updated CD containing the most recent bimonthly data is mailed with every new
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Watch,
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